A simple method for fabricating vertically stacked single-crystal silicon nanowires on standard bulk silicon wafers is presented. The process uses inductively coupled plasma (ICP) etching to create silicon fins with uneven yet controllable vertical profiles. The fins are then thermally oxidized in a self-limiting process, and the narrow regions are completely consumed to create multiple nanowires vertically stacked on each other. It was found that the number of nanowires in the vertical stack depends on the number of ICP cycles. A mechanism for the formation of the nanowires is proposed and confirmed with numerical simulations.
Posts Tagged ‘formation’
Fabrication of vertically stacked single-crystalline Si nanowires using self-limiting oxidation
Nanoimprint of dehydrated PEDOT:PSS for organic photovoltaics
We demonstrate the fabrication of poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanogratings by a dehydration-assisted nanoimprint lithographic technique. Dehydration of PEDOT:PSS increases its cohesion to protect the nanostructures formed by nanoimprinting during demolding, resulting in the formation of high quality nanogratings of 60 nm in height, 70 nm in width and 70 nm in spacing (aspect ratio of 0.86). PEDOT:PSS nanogratings are used as hole transport and an electron blocking layer in blended poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-penyl-C61-butyric-acid-methyl-ester (PCBM) organic photovoltaic devices (OPV), showing enhancement of photocurrent and power efficiency in comparison to OPV devices with non-patterned PEDOT:PSS films.
Polyacrylonitrile nanofibers prepared using coaxial electrospinning with LiCl solution as sheath fluid
A modified coaxial electrospinning process including an electrolyte solution as sheath fluid was used for preparing high quality polymer nanofibers. A series of polyacrylonitrile (PAN) nanofibers were fabricated utilizing a coaxial electrospinning containing LiCl in N , N -dimethylacetamide (DMAc) as the sheath fluid. FESEM results demonstrated that the sheath LiCl solutions have a significant influence on the quality of PAN nanofibers. Nanofibers with smaller diameters, smoother surfaces and uniform structures were successfully prepared. The diameters of nanofibers were controlled by adjusting the conductivity of the sheath fluid over a suitable range and this was determined by varying LiCl concentrations. The influence of the effect of LiCl on the formation of PAN fibers is discussed and it is concluded that coaxial electrospinning with electrolyte solutions is a convenient and facile process for achieving high quality polymer nanofibers.
The formation of micrometer-long TiO 2 nanotube arrays by anodization of titanium film on conducting glass substrate
Micrometer-long titanium oxide nanotube arrays, tens of nanometers in diameter, were fabricated by anodization of titanium film coated on a conducting glass substrate. The Ti film was deposited by magnetron sputtering at room temperature. The effect of anodizing conditions on the formation of TiO 2 nanotubes was investigated. The results indicate that dense and uniform Ti film deposited under 150 W at room temperature was favorable for the formation of ordered nanotube arrays. The average diameter of the TiO 2 nanotubes varied from 35 to 95 nm when the anodization potential changed from 10 to 40 V. Micrometer-long nanotubes (1.1 μm) with good adhesion to the substrate could be obtained in 0.5 wt% NH 4 F/glycerol at 30 V for 2 h. After heat treatment, the crystalline anatase nanotubes show enhanced photoelectrochemical activity compared with those anodized in 1 M H 3 PO 4 /0.5 wt% HF. This is attributed to the increased light-harvesti…
Enhanced tumor localization and retention of chlorin e6 in cationic nanolipoplexes potentiate the tumor ablation effects of photodynamic therapy
Here we report the tumor ablation effects of the negatively charged photosensitizer chlorin e6 (Ce6) in nanocomplexes. Ce6 was complexed to cationic 1,2-dioleoyl-sn-glycero-3-ethylphosphocholine-based liposomes, forming cationic nanolipoplexes. The loading efficiency of Ce6 to cationic nanolipoplexes was greater than 90%. The degree of enhancement of cellular uptake of Ce6 by treatment in cationic nanolipoplexes increased with the concentration of Ce6, showing 18.3-fold higher uptake than free Ce6 at15 µM. Molecular imaging revealed the preferential distribution and retention of Ce6 in SCC7 tumor tissues after intravenous administration of Ce6 in cationic nanolipoplexes. Moreover, localized illumination of mice receiving Ce6 in cationic nanolipoplexes resulted in the formation of thick scabs over tumor regions, and complete ablation of tumors after scab detachment. In contrast, continuous growth of tumors was observed in the group treated with free Ce6. Our results suggest that…
New Method For Nanoribbon Production
Researchers from Ulm University, Germany, and the University of Nottingham, UK, have pioneered a new method for making molecules that could lead toward faster, smaller, and more powerful nanomaterials for computers and data storage devices. The team has demonstrated that carbon nanotubes can be used as nanoscale chemical reactors, wherein chemical reactions involving carbon and sulphur atoms held within a nanotube lead to the formation of a thin strip of carbon, known as a graphene nanoribbon, decorated with sulphur atoms around the edge. “Graphene nanoribbons possess a wealth of interesting physical properties making them more suitable for applications in electronic and spintronic devices than the parent material graphene,” says Dr Andrei Khlobystov. “Nanoribbons are very difficult to make but the Nottingham team’s strategy of confining chemical reactions at the nanoscale sparks spontaneous formation of these remarkable structures. The team has also discovered that nanoribbons — far from being simple flat and linear structures — possess an unprecedented helical twist that changes over time, giving scientists a way of controlling physical properties of the nanoribbon, such as electrical conductivity.” Devices based on nanoribbons could potentially be used as nano-switches, nano-actuators and nano-transistors integrated in computers or data storage devices. Read More Paper
Controlled synthesis of gold nanoparticles by fluorescent light irradiation
A novel photochemical synthesis of size-controlled gold nanoparticles was reliably accomplished via both a direct reduction and a seeded-growth method at room temperature under the irradiation of fluorescent light. These methods utilized the intensity of fluorescent light that closely resembles daily sunlight (~100 mW cm − 2 ). This effectively allowed for the formation of gold nanoparticles with tunable sizes simply by controlling the concentration of trisodium citrate and gold chloride. The broad band fluorescent light was found to be an efficient source for inducing the formation of gold nanoparticles at ambient conditions. The size distribution and absorption property of the resulting nanoparticles were thoroughly characterized by scanning/transmission electron microscopy, dynamic light scattering, UV–visible spectroscopy and powder x-ray diffraction. This photochemical synthesis demonstrates, for the first time, the reliable preparation of gold nanoparticles at roo…
Extremely high response of electrostatically exfoliated few layer graphene to ammonia adsorption
Extremely high gas sensing properties of p-type few layer graphene flakes exfoliated from highly oriented pyrolytic graphite have been demonstrated. The current response to ammonia adsorption is strongly dependent on film thickness and is higher than that for graphene by 1–8 orders of magnitude. A maximal response was found for sample thickness ~ 2 nm. The effect is attributed to the formation of multiple p–n–p junctions at the grain boundaries in the polycrystalline graphene flakes exposed to ammonia-containing ambient.
One-dimensional pattern of Au nanodots by ion-beam sputtering: formation and mechanism
Highly ordered one-dimensional arrays of nanodots, or nanobeads, are fabricated by forming nanoripples and nanodots in sequence, entirely by ion-beam sputtering (IBS) of Au(001). This demonstrates the capability of IBS for the fabrication of sophisticated nanostructures via hierarchical self-assembly. The intricate nanobead pattern ideally serves to identify the governing mechanisms for the pattern formation: nonlinear effects, especially local redeposition and surface-confined transport, are essential both for the formation and the preservation of the one-dimensional order of the nanobead pattern.



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