Posts Tagged ‘Paper’

Temperature-dependent nonradiative recombination processes in GaN-based nanowire white-light-emitting diodes on silicon

In this paper, we have performed a detailed investigation of the temperature- and current-dependent emission characteristics of nanowire light-emitting diodes, wherein InGaN/GaN dot-in-a-wire nanoscale heterostructures and a p-doped AlGaN electron blocking layer are incorporated in the device’s active region to achieve white-light emission and to prevent electron overflow, respectively. Through these studies, the Auger coefficient is estimated to be in the range of ∼10 −34 cm 6 s −1 or less, which is nearly four orders of magnitude smaller than the commonly reported values of planar InGaN/GaN heterostructures, suggesting Auger recombination plays an essentially negligible role in the performance of GaN-based nanowire light-emitting diodes. It is observed, however, that the performance of such nanowire LEDs suffers severely from Shockley–Read–Hall recombination, which can account for nearly 40% of the total carrier recombination under moderate injecti…

Structure and morphology of platinum nanoparticles with critical new issues of low- and high-index facets

In this paper, Pt nanoparticles were successfully prepared by modified polyol method using silver nitrate as an effective structure-modifying agent. The characterization of Pt nanoparticles was investigated by using UV-Vis-NIR spectroscopy, transmission electron microscopy (TEM) and high resolution (HR) TEM, and x-ray diffraction (XRD). The method of selected area electron diffraction (SEAD) was used to study the structure of Pt nanoparticles. The results showed that the as-prepared Pt nanoparticles exhibiting the complexity of surface structure and morphology could be used as efficient catalysts for polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs).

Out-of-plane growth of CNTs on graphene for supercapacitor applications

This paper describes the fabrication and characterization of a hybrid nanostructure comprised of carbon nanotubes (CNTs) grown on graphene layers for supercapacitor applications. The entire nanostructure (CNTs and graphene) was fabricated via atmospheric pressure chemical vapor deposition (APCVD) and designed to minimize self-aggregation of the graphene and CNTs. Growth parameters of the CNTs were optimized by adjusting the gas flow rates of hydrogen and methane to control the simultaneous, competing reactions of carbon formation toward CNT growth and hydrogenation which suppresses CNT growth via hydrogen etching of carbon. Characterization of the supercapacitor performance of the CNT–graphene hybrid nanostructure indicated that the average measured capacitance of a fabricated graphene–CNT structure was 653.7 μF cm − 2 at 10 mV s − 1 with a standard rectangular cyclic voltammetry curve. Rapid charging–discharging characteristics (mV s − 1 ) were ex…

Wire-shaped quantum dots-sensitized solar cells based on nanosheets and nanowires

Wire-shaped quantum dots-sensitized solar cells (WS-QDSCs) based on nanosheets and nanowires were fabricated and investigated for this paper. The nanosheets grown on stainless steel (SS) wire by electrodeposition were mainly composed of Zn 5 (OH) 8 Cl 2 ·H 2 O and most of the Zn 5 (OH) 8 Cl 2 ·H 2 O was converted to ZnO by post-treatment, and ZnO nanowires were directly grown on SS wire by the hydrothermal method. CdS QDs were deposited on nanosheets and nanowires by successive ionic layer adsorption and reaction method. The results of photoelectrochemical performance indicated that WS-QDSCs showed a similar conversion efficiency in polysulfide and Na 2 SO 4 electrolytes, while the WS-QDSCs based on the Cu 2 S counter electrode achieved much higher performance than those based on SS and Cu counter electrodes. By optimizing electrodeposition duration, the WS-QDSCs based on nanosheet…

Some biomedical applications of chitosan-based hybrid nanomaterials

Being naturally abundant resources and having many interesting physicochemical and biological properties, chitin/chitosan have been found to be useful in many fields, especially biomedical ones. This paper describes the strategy to design multifunctional, hybrid chitosan-based nanomaterials and test them in some typical biomedical applications.

Room temperature observation of size dependent single electron tunneling in a sub-2 nm size tunable …

In this paper we report size dependent single electron tunneling behavior at room temperature in a metal–oxide–semiconductor structure with uniformly sized Pt nanoparticles embedded in an Al 2 O 3 dielectric. The sub-2 nm size Pt nanoparticles sandwiched between the Al 2 O 3 layers are deposited by a unique tilted target sputter deposition technique which produces metal nanoparticles as small as 0.5 nm with narrow size distributions at room temperature. The charging behavior of these nanoparticles shows clear single electron tunneling peaks due to the Coulomb blockade effect. Moreover, the average single electron addition energy and height of the single electron tunneling current strongly depend on the size of the Pt nanoparticle. These controllable single electron tunneling behaviors suggest a new route for fabrication of single electron devices.

Graphene oxide/ferrofluid/cement composites for electromagnetic interference shielding application

This paper deals with the preparation of graphene oxide–ferrofluid–cement nanocomposites to evaluate the electromagnetic interference (EMI) shielding effectiveness (SE) in the 8.2–12.4 GHz frequency range. It has been observed that incorporation of graphene oxide (30 wt%) along with an appropriate amount of ferrofluid in the cement matrix leads to a shielding effectiveness of 46 dB (> 99% attenuation).The presence of graphene oxide and ferrofluid in the cement leads to strong polarizations and magnetic losses that consequently result in higher shielding effectiveness compared to pristine cement. The resulting nanocomposites have shown Shore hardness of 54 and dc conductivity of 10.40 S cm − 1 . SEM reveals the homogeneous dispersion of graphene oxide and ferrofluid in the cement matrix.

Using post-breakdown conduction study in a MIS structure to better understand the resistive switching mechanism in an MIM stack

We apply our understanding of the physics of failure in the post-breakdown regime of high-κ dielectric-based conventional logic transistors having a metal–insulator–semiconductor (MIS) structure to interpret the mechanism of resistive switching in resistive random-access memory (RRAM) technology metal–insulator–metal (MIM) stacks. Oxygen vacancies, gate metal migration and metal filament formation in the gate dielectric which constitute the chemistry of breakdown in the post-breakdown stage of logic gate stacks are attributed to be the mechanisms responsible for the SET process in RRAM technology. In this paper, we draw an analogy between the breakdown study in logic devices and filamentation physics in resistive non-volatile memory.

Printed Paper Photovoltaic Cells

. Researchers from Chemnitz University of Technology and Julius-Maximilians-University of Würzburg, in Germany, have presented solar panels that are printed on standard paper. The technology, known as 3PV (3PV stands for printed paper photovoltaics) uses conventional printing methods and standard substrates, like those used for magazines, posters or packaging. Special inks with electrical properties form the necessary structures on paper, which ensure that electricity is generated when being exposed to light. The polymer/fullerene solar cells are printed on paper using a combination of gravure and flexographic printing techniques, and the cells are free from expensive electrodes made with indium–tin oxide, silver, or gold. Since conventional printing methods (i.e. gravure, flexo and offset printing) are very cost-efficient, the printed solar panels shall generate much cheaper electricity in comparison to conventional solar cells. Prof. Dr. Arved Hübler from the Institute for Print and Media Technology at Chemnitz University of Technology, who is working together with his research team on the 3PV technology for more than three years now, speaks of a paradigm shift in solar technology. His vision for the future is that common printing houses around the world could produce and market 3PV solar panels. The cells that were printed in Chemnitz achieve an energy conversion efficiency of 1.3 percent. The researchers use a new material approach. In a special printing process, naturally oxidized zinc is applied as base electrode. The transparent counter electrode is printed with PEDOT , a conductive polymer. “The materials are constantly optimised and we are confident that the 3PV parameters can be further improved,” says Tino Zillger, researcher and leader of the project. Even the team of Hübler is a bit surprised that it is already possible to produce very stable 3PV modules with a web printing press in the laboratory. “Our long experience in the field of printed electronics pays well here,” says the head of the chair Print Media Technology. Hübler assumes that all in all paper solar cells could have the edge over the current technological state of the art due to the efficient production and lower material costs. The aim of further research is to increase the efficiency to more than five percent in order to ensure that a 3PV module is economically attractive despite a life time of less than one year. “In nature we find a model for this strategy: even green leaves only have a moderate energy conversion efficiency of four to seven percent and a life time of less than one year. Nevertheless, this approach is obviously successful,” explains Hübler. The vision of being able to contribute to the overall energy supply with the help of paper solar panels is only one field of application. Researchers have already shown that it is also possible to drive small electrical devices with these paper solar cells. This opens up the possibility to supply mobile devices with “paper power” in a simple and self-sustaining way. Intelligent packaging, for instance, could include many additional features, ranging from displays to sensors. Handling of the paper solar cells can be very simple. The paper strips can be connected with the help of commercial snap fasteners. Immediately, an electrical current flows. According to the researchers, the paper modules can be recycled like any other waste paper after use. According to Hübler it is, thus, not only possible to generate renewable energy, but also the solar cell itself is made from renewable resources and is consequently renewable. Read More Paper

Edible Carbon Dioxide Sponge

A year ago, Northwestern University chemists published their recipe for a new class of nanostructures made of sugar, salt and alcohol. Now, the same team has discovered that the edible compounds can efficiently detect, capture and store carbon dioxide. And, the compounds themselves are carbon-neutral. The porous crystals — known as metal-organic frameworks ( MOF s) — are made from all-natural ingredients and are simple to prepare, giving them a huge advantage over other MOF s. Conventional MOF s, which also are effective at adsorbing carbon dioxide, are usually prepared from materials derived from crude oil and often incorporate toxic heavy metals. Other features of the Northwestern MOF s are they turn red when completely full of carbon dioxide, and the carbon capture process is reversible. “We are able to take molecules that are themselves sourced from atmospheric carbon, through photosynthesis, and use them to capture even more carbon dioxide,” said Ross S. Forgan, a co-author of the study. “By preparing our MOF s from naturally derived ingredients, we are not only making materials that are entirely nontoxic, but we are also cutting down on the carbon dioxide emissions associated with their manufacture.” The main component, gamma-cyclodextrin, is a naturally occurring biorenewable sugar molecule that is derived from cornstarch. The sugar molecules are held in place by metals taken from salts such as potassium benzoate or rubidium hydroxide, and it is the precise arrangement of the sugars in the crystals that is vital to their successful capture of carbon dioxide. “It turns out that a fairly unexpected event occurs when you put that many sugars next to each other in an alkaline environment — they start reacting with carbon dioxide in a process akin to carbon fixation, which is how sugars are made in the first place,” said Jeremiah J. Gassensmith, lead author of the paper. “The reaction leads to the carbon dioxide being tightly bound inside the crystals, but we can still recover it at a later date very simply.” The fact that the carbon dioxide reacts with the MOF , an unusual occurrence, led to a simple method of detecting when the crystals have reached full capacity. The researchers place an indicator molecule, which detects changes in pH by changing its color, inside each crystal. When the yellow crystals of the MOF s are full of carbon dioxide they turn red. The simplicity of the new MOF s, allied with their low cost and green credentials, have marked them as candidates for further commercialization. Ronald A. Smaldone, a co-author of the paper, added, “I think this is a remarkable demonstration of how simple chemistry can be successfully applied to relevant problems like carbon capture and sensor technology.” Read More Paper