Posts Tagged ‘Technology’

Fast nanoscale 3D-printing (link to video)

285-micron racecar (credit: Vienna University of Technology) For those interested in atomically precise manufacturing, 3D-printing is an interesting microscale technology for making centimeter-scale objects. We commented on this technology a few months ago with the introduction of two competing technologies for printing complex digitally-designed plastic consumer items. Foresight Senior Associate Charles Vollum sends word of the extension of 3D-printing to nanoscale (approximately 100 nm) resolution. In addition, the new procedure is much faster and enables true 3D fabrication, without requiring layer-by-layer fabrication. A hat tip to KurzweilAI for describing this Vienna University of Technology news release “ 3D-printer with nano-precision “: Printing three dimensional objects with incredibly fine details is now possible using “two-photon lithography”. With this technology, tiny structures on a nanometer scale can be fabricated. Researchers at the Vienna University of Technology (TU Vienna) have now made a major breakthrough in speeding up this printing technique: The high-precision-3D-printer at TU Vienna is orders of magnitude faster than similar devices (see video). This opens up completely new areas of application, such as in medicine. The video shows the 3d-printing process in real time. Due to the very fast guiding of the laser beam, 100 layers, consisting of approximately 200 single lines each, are produced in four minutes. Setting a New World Record The 3D printer uses a liquid resin, which is hardened at precisely the correct spots by a focused laser beam. The focal point of the laser beam is guided through the resin by movable mirrors and leaves behind a polymerized line of solid polymer, just a few hundred nanometers wide. This high resolution enables the creation of intricately structured sculptures as tiny as a grain of sand. “Until now, this technique used to be quite slow”, says Professor J

Atomically-precise positioning of a single atom transistor-VIDEO

A team led by Michelle Y. Simmons, who spoke on “Atomic-scale device fabrication in silicon” at the 2007 Productive Nanosystems: Launching the Technology Roadmap conference, which introduced the Technology Roadmap for Productive Nanosystems , has succeeded in the atomically precise placement of a transistor consisting of a single atom of phosphorous between source and drain electrodes and gate electrodes all made from phosphorous wires only a few atoms wide. A YouTube video illustrating this working transistor of a single atom of phosphorous placed with atomic precision on a silicon crystal includes an STM image that shows the single phosphorous atom placed several tens of rows of silicon atoms from source and drain electrodes of phosphorous that appear to be about 10 rows of atoms wide. To manufacture the phosphorous transistor and electrodes, a scanning tunneling microscope was used to remove precisely determined hydrogen atoms from the passivating layer covering a silicon crystal to form a mask that was then used to apply phosphorous atoms to the vacancies created. An overlay of silicon atoms then preserved these phosphorous nanostructures. The accomplishment is described in a NY Times article by John Markoff, which describes both the place of this work in the progression of Moore’s Law and its potential for a new generation of quantum computers: “ Physicists Create a Working Transistor From a Single Atom “: Australian and American physicists have built a working transistor from a single phosphorus atom embedded in a silicon crystal. The group of physicists, based at the University of New South Wales and Purdue University, said they had laid the groundwork for a futuristic quantum computer that might one day function in a nanoscale world and would be orders of magnitude smaller and quicker than today’s silicon-based machines. … “Their approach is extremely powerful,” said Andreas Heinrich, an I.B.M. physicist. “This is at least a 10-year effort to make very tiny electrical wires and combine them with the placement of a phosphorous atom exactly where they want them.” He said the research was a significant step toward making a functioning quantum computing system. However, whether quantum computing will ever be harnessed for useful tasks remains uncertain, and the researchers also noted that their work demonstrated the fundamental limits that today’s computers would be able to shrink to. “It shows that Moore’s Law can be scaled toward atomic scales in silicon,” said Gerhard Klimeck, professor of electrical and computer engineering at Purdue, referring to the rate at which computing gets faster and cheaper. “The technologies for classical computing can survive to the atomic scale.” The results were published in Nature Nanotechnology [ abstract ]. At least for the moment (February 19, 2012), the full text is available without charge. Also available in the same issue is a commentary by Gabriel P. Lansbergen “ Nanoelectronics: Transistors arrive at the atomic limit “, which gives additional background and details on this accomplishment. … Single-atom transistors represent the ultimate limit in solid-state device miniaturization, but they are also interesting for another reason. Deterministically positioned single-dopant atoms in silicon, electrically addressable by metallic leads, are at the heart of a number of promising proposals for quantum-information-processing devices3. The long coherence and relaxation times associated with single dopants make them very attractive candidates for quantum-device architectures. The atom-by-atom fabrication technique developed by Simmons and co-workers therefore fulfills a long-standing need for a method that is capable of atomic-scale device fabrication in silicon. And although the technique is not directly applicable on an industrial scale, it does bring the development of truly atomistic electronics — and the possibilities they offer — into the experimental realm. This latest accomplishment from Prof. Simmons and her collaborators follows swiftly on their recent demonstration published just last month in Science [ abstract ], that Ohms law holds for nanowire only four phosphorous atoms wide. From the Purdue University news service “ Down to the wire for silicon: Researchers create a wire 4 atoms wide, 1 atom tall “: The smallest wires ever developed in silicon – just one atom tall and four atoms wide – have been shown by a team of researchers from the University of New South Wales, Melbourne University and Purdue University to have the same current-carrying capability as copper wires. Experiments and atom-by-atom supercomputer models of the wires have found that the wires maintain a low capacity for resistance despite being more than 20 times thinner than conventional copper wires in microprocessors. The discovery, which was published in this week’s journal Science, has several implications, including: For engineers it could provide a roadmap to future nanoscale computational devices where atomic sizes are at the end of Moore’s law. The theory shows that a single dense row of phosphorus atoms embedded in silicon will be the ultimate limit of downscaling. For computer scientists, it places donor-atom based silicon quantum computing closer to realization. And for physicists, the results show that Ohm’s Law, which demonstrates the relationship between electrical current, resistance and voltage, continues to apply all the way down to an atomic-scale wire. … Although the path from this laboratory demonstration to a practical technology is not yet clear, as emphasized above by the researchers themselves and commentators, the progress at Zyvex Labs (and elsewhere) that we cited in Oct. 2010 in this basic technology of using an STM for atomically precise lithography holds hope that a convergence of manufacturing technology and demonstrated prototypes will not be too distant. —James Lewis

Single Molecule Analysis

. Oxford Nanopore Technologies Ltd is developing a novel technology for direct, electronic detection and analysis of single molecules using nanopores. Their miniaturized device is the size of a USB memory stick, and is designed for portable analysis of single molecules. Oxford Nanopore intends to commercialize the technology directly to customers for DNA ‘strand sequencing’ in 2012. In addition to DNA sequencing, the system is also compatible with the direct analysis of RNA . Oxford Nanopore is also developing a Protein Analysis technology that combines target proteins with ligands for direct, electronic analysis using protein nanopores. The Company is also developing the subsequent generation of nanopore sensing devices based on solid-state nanopores. Read More

Nanodynamite Provides Power

. Researchers at the Massachusetts Institute of Technology ( MIT ) and RMIT University have made a breakthrough in energy storage and power generation. The power generated relative to the energy source size is three to four times greater than what is currently possible with the best lithium-ion batteries. While on sabbatical from RMIT in 2009 and 2010, Associate Professor Dr Kourosh Kalantar-zadeh joined MIT Associate Professor Michael Strano’s nanotechnology research group. Before he arrived, Strano’s laboratory was working on measuring the acceleration of a chemical reaction along a nanotube when they discovered that the reaction generated power. Kalantar-zadeh said that this experimental system, based on one of the materials that have come from nanotechnology – carbon nanotubes – generates power, something researchers had not seen before. “By coating a nanotube in nitrocellulose fuel and igniting one end, we set off a combustion wave along it and learned that a nanotube is an excellent conductor of heat from burning fuel. Even better, the combustion wave creates a strong electric current,” he said. Read More Read More

Zeolites Open Opportunity For Carbon Capture

. Filtering carbon dioxide, a greenhouse gas, from factory smokestacks is a necessary, but expensive part of many manufacturing processes. However, a collaborative research team from the National Institute of Standards and Technology ( NIST ) and the University of Delaware has gathered new insight into the performance of a material called a zeolite that may stop carbon dioxide in its tracks far more efficiently than current scrubbers do. Zeolites are highly porous rocks—think of a sponge made of stone—and while they occur in nature, they can be manufactured as well. Their toughness, high surface area (a gram of zeolite can have hundreds of square meters of surface in its myriad internal chambers) and ability to be reused hundreds of times makes them ideal candidates for filtering gas mixtures. If an unwanted molecule in the gas mixture is found to stick to a zeolite, passing the mixture through it can scrub the gas of many impurities, so zeolites are widely used in industrial chemistry as catalysts and filters. The team explored a zeolite created decades ago in an industrial lab and known by its technical name, SSZ -13. This zeolite, which has octagonal “windows” between its interior pore spaces, is special because it seems highly capable of filtering out carbon dioxide (CO2) from a gas mixture. “That makes SSZ -13 a promising candidate for scrubbing this greenhouse gas out of such things as factory smokestacks,” says Craig Brown, a researcher at the NIST Center for Neutron Research ( NCNR ). “So we explored, on an atomic level, how it does this so well.” Using neutron diffraction, the team determined that SSZ -13’s eight-sided pore windows are particularly good at attracting the long, skinny carbon dioxide molecules and holding onto their “positively-charged” central carbon atoms, all the while allowing other molecules with different shapes and electronic properties to pass by unaffected. Like a stop sign, each pore halts one CO2 molecule—and each cubic centimeter of the zeolite has enough pores to stop 0.31 grams of CO2, a quantity that makes SSZ -13 highly competitive when compared to other adsorbent materials. Brown says a zeolite like SSZ -13 probably will become a prime candidate for carbon scrubbing because it also could prove more economical than other scrubbers currently used in industry. SSZ -13’s ability to attract only CO2 could mean its use would reduce the energy demands of scrubbing, which can require up to 25 percent of the power generated in a coal or natural gas power plant. “Many industrial zeolites attract water and carbon dioxide, which are both present in flue exhaust—meaning both molecules are, in a sense, competing for space inside the zeolite,” Brown explains. “We suspect that this novel CO2 adsorption mechanism means that water is no longer competing for the same site. A zeolite that adsorbs CO2 and little else could create significant cost savings, and that’s what this one appears to do.” Brown says his team is still collecting data to confirm this theory, and that their future efforts will concentrate on exploring whether SSZ -13 is equally good at separating CO2 from methane—the primary component of natural gas. CO2 is also released in significant quantities during gas extraction, and the team is hopeful SSZ -13 can address this problem as well. Read More

Holographic 3-D Displays

. Applications like holographic TV have long been relegated as the next big thing in the distant future but a Belgium-based R&D lab for nanoelectronics has come up with a process that might bring holographic images closer to realtime. At Imec, their work involves creating moving pixels. They are constructing holographic displays by shining lasers on microelectromechanical systems ( MEMS ) platforms that can move up and down like small, reflective pistons. “Holographic visualization promises to offer a natural 3-D experience for multiple viewers, without the undesirable side-effects of current 3D stereoscopic visualization (uncomfortable glasses, strained eyes, fatiguing experience),” the company states. In their nanoscale system, they work with chips made by growing a layer of silicon oxide on to silicon wafer. They etch square patches of the silicon oxide. The result is a checkerboard-like pattern where etched-away pixels are nanometers lower than their neighbors. A reflective aluminum coating tops the chip. When laser light shines on the chip, it bounces off of the boundary between adjacent pixels at an angle. Diffracted light interferes constructively and destructively to create a 3-D picture where small mirrored platforms are moving up and down, many times a second, to create a moving projection. The process can also be described as the pixels closer to the light interfering with it one way and those further off, in another. The small distances between them generate the image that the eye sees. Imec hopes to construct the first, proof-of-concept moving structures by mid-2012. “Imec’s vision is to design the ultimate 3D display: a holographic display with a 60° diffraction angle and a high-definition visual experience,” they state. As such, Imec will have lots of company elsewhere in the race to iron out complexities of holographic imaging. According to reports throughout 2011, research teams aim to make the technology more of a reality than a wish-list item for consumers. The BBC R&D department has identified the work that broadcasters are doing across Europe, for example, in holographic TV. Engineers are also focused on research into 3-D holoscopy for the Internet and other 3-D applications. Researchers at MIT this year said they were closing in on holographic TV by building a system with a refresh rate of 15 frames per second. Also earlier this year, the Defense Advanced Research Projects Agency ( DARPA ) completed a five-year project called Urban Photonic Sandtable Display that creates realtime, color, 360-degree 3-D holographic displays. Read More Read More

Lecture by Eric Drexler at Oxford on physical law and the future of nanotechnology (video)

Eric Drexler presented a lecture at the University of Oxford Oxford Martin Programme on the Impacts of Future Technology that addressed two key questions: What will be the next great revolution in the material basis of civilization? How can we establish reliable knowledge about key aspects of such technologies? From the news release, aptly titled “ The next technological revolution? “: The key to tackling some of our planet’s greatest challenges may be found in the laws of physics and methods of engineering, as opposed to any specific technological innovation. Speaking at the inaugural public lecture of the Oxford Martin Programme on the Impacts of Future Technology, Dr Eric Drexler said there is a compelling case for the viability of atomically precise manufacturing. This is the process of building structures, tools and machines starting at the molecular level, with atomic precision, to address challenges such as rising greenhouse gases and energy production for our growing population. In a talk entitled “Exploring a Timeless Landscape: Physical Law and the Future of Nanotechnology”, pioneering nanotechnology researcher Dr. Drexler invited the audience to consider the intriguing possibility of nano-level manufacture of macro-level products. Such a process, if achieved, would be the next great revolution in the material basis of civilization, offering high-performance components, materials or systems and accelerated productivity. … Those who have read Drexler’s 1988 essay on exploratory engineering and the 2007 Technology Roadmap for Productive Nanosystems will be familiar with the main arguments presented in the talk. Dr. Drexler’s conclusions about the development of atomically precise manufacturing were: We now have ample scientific knowledge. Rather than additional breakthroughs we need component design. Molecular experiments are fast and inexpensive by ordinary engineering standards. Advances in fabrication methods will yield faster more predictable results, accelerating progress. Dr. Drexler left the audience to consider whether the advent of atomically precise manufacturing meant that in preparing for the 21st century we should expect scarcity and conflict or something radically different, and whether we could change the conversation in the world about the future incrementally in a well-grounded way. The Oxford Martin Programme has made the abstract available, which includes a link to a Youtube video of the lecture “ Timeless Landscape: Physical Law and the Future of Nanotechnology “.

Nanocomposite Cathodes For Field Emission Devices

Field emission devices, which produce a steady stream of electrons, have a host of consumer, industrial, and research applications. But even though recent designs based on nanotubes and other nanomaterials embedded in plastics show initial promise, they have a number of drawbacks that hinder their wide-scale application. The embedded nanotubes, which serve as the source for the electrons, enable the normally inert plastic to conduct electricity, producing the desired result of a versatile and easily manufactured field emission device. But since plastics are, by nature, poor conductors of electricity, they require a high concentration of nanomaterials to function. Plastics also have low thermal stability and do not hold up well under the excess heat produced by prolonged operation. Now, a team of researchers from Monash University in Australia, in collaboration with colleagues from CSIRO Process Science and Engineering, has developed a promising and easily manufactured replacement for plastics: amorphous bulk metallic glass ( ABM ). These ABM alloys form amorphous materials as they cool, giving them more of a glass-like behavior. The researchers used an alloy made from magnesium, copper, and gadolinium. This metallic glass has many of plastics’ desirable features. It can conform to a variety of shapes, be produced in bulk, and serve as an effective matrix for the nanotubes. Besides its high conductivity, the metallic glass’ highly robust thermal properties mean that it can withstand high temperatures and still retain its shape and durability. According to the researchers, these advantages, alongside excellent electron emission properties, make these composites one of the best reported options for electron emission applications to date. Though other composites of bulk metallic glass and carbon nanotubes have been reported before, this is the first time that such a system is being used for a functional device, such as for field emission. Electron microscopes, microwave or X-ray generation, nano-electronics, and modern display devices are all examples of the potential applications of this technology, the researchers note. Read More Paper

Leveraging nanoforces to increase biosensor sensitivity

This contribution has been forwarded by Ivo Rivetta. The primary forces on the nanometer scale are scaled versions of what we experience on a day to day basis. Instead of gravity, surface forces such as water tension and electric charge dominate. As an example, compare wet basketballs and wet sand. The weight of the basketballs overpowers the surface forces that water introduces but wet sand particles clump together despite the fact that gravity is still trying to pull them apart. Researchers at the National Institute of Standards and Technology (NIST) take advantage of this phenomena in the design of a Gold nanoparticle biosensor for HCG, a pregnancy hormone. The detection mechanism is based on the fact that nanoparticles absorb characteristic frequencies of light based on the size of their clusters. The larger the cluster, the more light is absorbed by lower frequencies. Light absorption is a common way to gauge the size of individual nanoparticles but NIST researchers are the first to correlate the absorbed frequencies of light specifically to cluster size. The next step in designing a sensor is establishing the minimum detection threshold for nanoparticles bound to HCG versus unbound nanoclusters. Quote from: NIST Press Release: http://www.nist.gov/mml/biochemical/cluster-102511.cfm

Four-Wheeled Electric NanoCar

A nanoscale ‘car’ is the latest example of how nanoscale systems designed to imitate functions from the macroscopic world are leading to a new appreciation of the complexity that is needed to actuate motion at the limits of miniaturization. The nanocar was created by researchers from University of Groningen in The Netherlands, the Swiss Federal Laboratories for Materials Science and Technology, and the University of Zurich. The specially designed molecule has four motorized ‘wheels’. By depositing the molecules on a surface and providing them with sufficiently energetic electrons from the tip of a scanning tunneling microscope, the researchers were able to drive some of the molecules in a specific direction, much like a car with four-wheel drive. Previous examples of actuated single-molecule motion have been reported by others, but none with the complex action to continue moving in the same direction across a surface like the system devised, synthesized and operated by the team. In such work, the forces that dominate the macroscopic world around us, such as gravity, are less important than the forces that rule the nanoscale and biological worlds, such as van der Waals and capillary forces. Nevertheless, there are similarities between our everyday world and the nanoscale world: a car must have not only the ability to accelerate, but also brakes and traction; likewise, nanoscale actuated motion depends on balancing applied forces with those that hold structures in place. The researchers solved this problem, as others have, by balancing surface interactions and thermal energy with forces that can be applied through actuation, so that their molecules move only on stimulation, rather than by diffusion. Read More Paper Movie 1 (.mov) Movie 2 (.mov) Movie 3 (.mov) Movie 4 (.mov)