Posts Tagged ‘Work’

Silicene Grown On Templates

. The fascination with two-dimensional materials that has started with graphene has spurred researchers to look for other 2D structures, such as metal carbides and nitrides. One particularly interesting analogue to graphene would be 2D silicon – silicene – because it could be synthesized and processed using mature semiconductor techniques, and more easily integrated into existing electronics than graphene is currently. However, silicene does not seem to exist in nature nor is there any solid phase of silicon similar to graphite. Nevertheless, silicene has been predicted by theory as early as 1994 and, with the explosive research going into graphene, there has been growing interest in this field over the past few years. In recent work by researchers at TU-Berlin, CNRS -CINaM in Marseille, CNR – ISM in Rome, and the Synchrotron SOLEIL in Saint Aubin, have presented the first clear evidence for the synthesis and thus the existence of silicene – a two-dimensional material, with a honeycomb-like arrangement of silicon atoms. “The most important motivation for our work was to demonstrate the existence of silicene by growing it on templates that do not react with the silicon atoms, such as Ag(111) surfaces,” explains Patrick Vogt. “In the literature, there has been only one publication (“Epitaxial growth of a silicene sheet”) before which claims the synthesis of silicene on Ag(111) based on STM measurements only. We explain in our manuscript why we are convinced that these results only refer to measurements of a clean Ag(111) surface. This is not the first time in research that STM measurements are misleading in order to find an atomic structural model. Furthermore, the pure Ag(111) surface can sometimes appear as a honeycomb structure due to an electronic effect caused by the STM tip.” Read More Paper

A silicon/zinc 2,9,16,23-tetraaminophthalocyanine coaxial core–shell nanowire array as an efficient solar hydrogen generation photocatalyst

In this work, we have demonstrated that a silicon nanowire (SiNW) array can be an efficient visible light photocatalyst for hydrogen generation after being modified by the 2,9,16,23-tetraaminophthalocyanine of zinc (ZnTAPc). A photoelectrochemical (PEC) cell employing a ZnTAPc modified SiNW array as photoanode was found to be able to effectively produce hydrogen at a rate of 13 µmol (cm 2 h) −1 under 100 mw cm −2 irradiation from a xenon lamp. It is believed that the loading of ZnTAPc can enhance the efficiency of hydrogen generation and the stability of the SiNW array. This demonstrates that the ZnTAPc modified SiNW is a promising material for solar hydrogen generation.

Fabrication and surface-modification of implantable microprobes for neuroscience studies

In this work implantable micro-probes for central nervous system (CNS) studies were developed on silicon and polyimide substrates. The probes which contained micro-electrode arrays with different surface modifications were designed for implantation in the CNS. The electrode surfaces were modified with nano-scale structures that could greatly increase the active surface area in order to enhance the electrochemical current outputs while maintaining micro-scale dimensions of the electrodes and probes. The electrodes were made of gold or platinum, and designed with different sizes. The silicon probes were modified by silicon nanowires fabricated with the vapor–liquid–solid mechanism at high temperatures. With polyimide substrates, the nanostructure modification was carried out by applying concentrated gold or silver colloid solutions onto the micro-electrodes at room temperature. The surfaces of electrodes before and after modification were observed by scanning electron microscopy. T…

Inspiring Matter @ The RCA

. The inaugural Inspiring Matter conference is underway at the Royal College of Art in London. The conference has gathered some of the world’s leading designers, scientists, artists, and anthropologists to discuss materials research and innovation. Over the next two days, presenters are expected to talk about how they work across disciplines and find inspiration in their work with materials. Hosted by the RCA‘s Materials for Living Hub and the Materials and Design Exchange of the MATERIALS KTN in the UK, Inspiring Matter is the beginning of a new RCA -based community which will facilitate useful and inspiring dialogue across materials-related disciplines. The event features a large list of well-known speakers, including: physicist Sir Richard Friend (University of Cambridge), Anna Valtonen (ex Head, Nokia design-research, now Rector, Umea Design Institute), architect Mike Davies (Rogers Stirk Harbour), anthropologist Susanne Küchler (University College London), artist Daisy Ginsberg, designers Fiona Raby & Tony Dunne (Dunne & Raby), historian Sarah Teasley ( RCA ), and architect Peter Yeadon (Partner, Decker Yeadon LLC , New York City). Read More

Atomically-precise positioning of a single atom transistor-VIDEO

A team led by Michelle Y. Simmons, who spoke on “Atomic-scale device fabrication in silicon” at the 2007 Productive Nanosystems: Launching the Technology Roadmap conference, which introduced the Technology Roadmap for Productive Nanosystems , has succeeded in the atomically precise placement of a transistor consisting of a single atom of phosphorous between source and drain electrodes and gate electrodes all made from phosphorous wires only a few atoms wide. A YouTube video illustrating this working transistor of a single atom of phosphorous placed with atomic precision on a silicon crystal includes an STM image that shows the single phosphorous atom placed several tens of rows of silicon atoms from source and drain electrodes of phosphorous that appear to be about 10 rows of atoms wide. To manufacture the phosphorous transistor and electrodes, a scanning tunneling microscope was used to remove precisely determined hydrogen atoms from the passivating layer covering a silicon crystal to form a mask that was then used to apply phosphorous atoms to the vacancies created. An overlay of silicon atoms then preserved these phosphorous nanostructures. The accomplishment is described in a NY Times article by John Markoff, which describes both the place of this work in the progression of Moore’s Law and its potential for a new generation of quantum computers: “ Physicists Create a Working Transistor From a Single Atom “: Australian and American physicists have built a working transistor from a single phosphorus atom embedded in a silicon crystal. The group of physicists, based at the University of New South Wales and Purdue University, said they had laid the groundwork for a futuristic quantum computer that might one day function in a nanoscale world and would be orders of magnitude smaller and quicker than today’s silicon-based machines. … “Their approach is extremely powerful,” said Andreas Heinrich, an I.B.M. physicist. “This is at least a 10-year effort to make very tiny electrical wires and combine them with the placement of a phosphorous atom exactly where they want them.” He said the research was a significant step toward making a functioning quantum computing system. However, whether quantum computing will ever be harnessed for useful tasks remains uncertain, and the researchers also noted that their work demonstrated the fundamental limits that today’s computers would be able to shrink to. “It shows that Moore’s Law can be scaled toward atomic scales in silicon,” said Gerhard Klimeck, professor of electrical and computer engineering at Purdue, referring to the rate at which computing gets faster and cheaper. “The technologies for classical computing can survive to the atomic scale.” The results were published in Nature Nanotechnology [ abstract ]. At least for the moment (February 19, 2012), the full text is available without charge. Also available in the same issue is a commentary by Gabriel P. Lansbergen “ Nanoelectronics: Transistors arrive at the atomic limit “, which gives additional background and details on this accomplishment. … Single-atom transistors represent the ultimate limit in solid-state device miniaturization, but they are also interesting for another reason. Deterministically positioned single-dopant atoms in silicon, electrically addressable by metallic leads, are at the heart of a number of promising proposals for quantum-information-processing devices3. The long coherence and relaxation times associated with single dopants make them very attractive candidates for quantum-device architectures. The atom-by-atom fabrication technique developed by Simmons and co-workers therefore fulfills a long-standing need for a method that is capable of atomic-scale device fabrication in silicon. And although the technique is not directly applicable on an industrial scale, it does bring the development of truly atomistic electronics — and the possibilities they offer — into the experimental realm. This latest accomplishment from Prof. Simmons and her collaborators follows swiftly on their recent demonstration published just last month in Science [ abstract ], that Ohms law holds for nanowire only four phosphorous atoms wide. From the Purdue University news service “ Down to the wire for silicon: Researchers create a wire 4 atoms wide, 1 atom tall “: The smallest wires ever developed in silicon – just one atom tall and four atoms wide – have been shown by a team of researchers from the University of New South Wales, Melbourne University and Purdue University to have the same current-carrying capability as copper wires. Experiments and atom-by-atom supercomputer models of the wires have found that the wires maintain a low capacity for resistance despite being more than 20 times thinner than conventional copper wires in microprocessors. The discovery, which was published in this week’s journal Science, has several implications, including: For engineers it could provide a roadmap to future nanoscale computational devices where atomic sizes are at the end of Moore’s law. The theory shows that a single dense row of phosphorus atoms embedded in silicon will be the ultimate limit of downscaling. For computer scientists, it places donor-atom based silicon quantum computing closer to realization. And for physicists, the results show that Ohm’s Law, which demonstrates the relationship between electrical current, resistance and voltage, continues to apply all the way down to an atomic-scale wire. … Although the path from this laboratory demonstration to a practical technology is not yet clear, as emphasized above by the researchers themselves and commentators, the progress at Zyvex Labs (and elsewhere) that we cited in Oct. 2010 in this basic technology of using an STM for atomically precise lithography holds hope that a convergence of manufacturing technology and demonstrated prototypes will not be too distant. —James Lewis

Defect-driven synthesis of self-assembled single crystal titanium nanowires via electrochemistry

One-dimensional single crystal nanostructures have garnered much attention, from their low-dimensional physics to their technological uses, due to their unique properties and potential applications, from sensors to interconnects. There is an increasing interest in metallic titanium nanowires, yet their single crystal form has not been actualized. Vapor–liquid–solid (VLS) and template-assisted top-down methods are common means for nanowire synthesis; however, each has limitations with respect to nanowire composition and crystallinity. Here we show a simple electrochemical method to generate single crystal titanium nanowires on monocrystalline NiTi substrates. This work is a significant advance in addressing the challenge of growing single crystal titanium nanowires, which had been precluded by titanium’s reactivity. Nanowires grew non-parallel to the surface and in a periodic arrangement along specific substrate directions; this behavior is attributed to a defect-driven mechanism….

Preparation and characterization of titanium dioxide nanotube array supported hydrated ruthenium oxide catalysts

This work aimed at preparing and characterizing TiO 2 nanotube supported hydrated ruthenium oxide catalysts. First of all, we succeeded in preparing TiO 2 nanotube arrays by electrochemical anodization of titanium metal at 20 V for 8 h in a 1M H 3 PO 4 +0.5 wt% HF solution as evidenced from scanning electron microscopy (SEM) and x-ray photoelectron spectroscopy ( XPS) results. The hydrated ruthenium oxide was then deposited onto TiO 2 nanotubes by consecutive exchange of protons by Ru 3+ ions, followed by formation of hydrated oxide during the alkali treatment. Further XPS measurements showed that the modified samples contain not only hydrated ruthenium oxide but also hydrated ruthenium species Ru(III)-OH.

Visible light responsive titania-based nanostructures for photocatalytic, photovoltaic and photoelectrochemical applications

This work presents a topical review of selected articles on visible light responsive titania-based nanostructures used for fabricating the photoanodes of the photocatalytic and photoelectrical cells for hydrogen production by water splitting or fuel decomposition, electricity generation by fuel decomposition and pollutant degradation under illumination by sunlight as well as for fabricating dye-sensitized and quantum dot-sensitized solar cells. Three main types of related nanostructures are reviewed: anion-doped titania nanomaterials, cation-doped titania nanomaterials and titania-based nanostructures sensitized by dyes and quantum dots. After the presentation of the obtained results, the prospective further research works to achieve the successful fabrication of visible light responsive photocatalytic, photoelectrochemical or photovoltaic devices with high performance are discussed.

DNA motor navigates network of DNA tracks

The structural DNA path toward productive nanosystems has achieved another step forward with the demonstration that a DNA origami scaffolding can be used to program a DNA motor to navigate a network of tracks. A hat tip to PhysOrg.com for reprinting this news release from Kyoto University “ DNA Motor Programmed to Navigate a Network of Tracks “: Kyoto, Japan — Expanding on previous work with engines traveling on straight tracks, a team of researchers at Kyoto University and the University of Oxford have successfully used DNA building blocks to construct a motor capable of navigating a programmable network of tracks with multiple switches. The findings, published in the January 22 online edition of the journal Nature Nanotechnology [ abstract ], are expected to lead to further developments in the field of nanoengineering. The research utilizes the technology of DNA origami, where strands of DNA molecules are sequenced in a way that will cause them to self-assemble into desired 2D and even 3D structures. In this latest effort, the scientists built a network of tracks and switches atop DNA origami tiles, which made it possible for motor molecules to travel along these rail systems. “We have demonstrated that it is not only possible to build nanoscale devices that function autonomously,” explained Dr. Masayuki Endo of Kyoto University’s Institute for Integrated Cell-Material Sciences (iCeMS), “but that we can cause such devices to produce predictable outputs based on different, controllable starting conditions.” The team, including lead author Dr. Shelley Wickham at Oxford, expects that the work may lead to the development of even more complex systems, such as programmable molecular assembly lines and sophisticated sensors. “We are really still at an early stage in designing DNA origami-based engineering systems,” elaborated iCeMS Prof. Hiroshi Sugiyama. “The promise is great, but at the same time there are still many technical hurdles to overcome in order to improve the quality of the output. This is just the beginning for this new and exciting field.” Courtesy Sugiyama Lab, Kyoto University iCeMS A depiction of a DNA origami tile with a built-in network of tracks. The DNA engine or motor, in red, can be programmed to navigate a series of junctions to reach one of four desired end points. Perhaps the next step is to have multiple addressable DNA motors bring different components together to be joined? —James Lewis

Effect of top-down nanomachining on electrical conduction properties of TiO 2 nanostructure-based chemical sensors

The present research was motivated by the growing interest of the scientific community towards the understanding of basic gas–surface interaction mechanisms in 1D nanostructured metal oxide semiconductors, whose significantly enhanced chemical detection sensitivity is known. In this work, impedance spectroscopy (IS) was used to evaluate how a top-down patterning of the sensitive layer can modulate the electrical properties of a gas sensor based on a fully integrated nanometric array of TiO 2 polycrystalline strips. The aim of the study was supported by comparative experimental activity carried out on different thin film gas sensors based on identical TiO 2 polycrystalline sensitive thin films. The impedance responses of the investigated devices under dry air (as the reference environment) and ethanol vapors (as the target gas) were fitted by a complex nonlinear least-squares method using LEVM software, in order to find an appropriate equivalent circuit describ…